MORPHOLOGICAL AND VIBRATIONAL CHARACTERIZATIONS OF SnO2 NANO MATERIAL USING COMPUTATIONAL CALCULATIONS

Abstract

In this research work, SnO2 Nano material was prepared using popular sol-gel combustion route. The XRD characterization was made along with the results obtained from the computational calculations. The inter planes of the crystals have been identified and the (000), (111), (222), (110), and (220) sequence of translational symmetry was keenly analyzed. The optimized parameters were calculated at different temperatures and they were compared with experimental results. The crystal lattice constants were calculated and the results were found to be supported the observed data. The Vibrational assignments made upon which the active compositional parts of the SnO2 compound were recognized. The active IR and Raman bands of Sn-O bonds at different planes causing XRD peaks with maximum intensity were ensured. As the topographical effect of present nano system of particles was enabled, the molecular arrangement of crystal system was found to be having enriched surface area. The kubo gap of the prepared and the materials with annealing temperatures were determined and compared with calculated values at IR and UV-Visible regions. The light dispersion coefficient of the SnO2 material was found and the relative parameters were calculated from the polarizability and hyperpolarizability constants. The frontier interactions profile was mapped and the cause of gas sensing property was studied. 

 [tnc-pdf-viewer-iframe file=”http://starresearchjournal.com/wp-content/uploads/2018/10/v6i10p1.pdf” width=”100%” height=”1000px” download=”true” print=”true” fullscreen=”true” share=”true” zoom=”true” open=”true” pagenav=”true” logo=”true” find=”true” language=”en-US” page=”” default_zoom=”auto” pagemode=””]Keywords: SnO2, Raman bands, Sn-O, dispersion, Kubo gap, polarizability and hyperpolarizability.

32 Comments

  1. The directives largely roll back efforts made over the last decade attempting to eradicate toxic culture in the military, both to decrease harmful behaviors like harassment, but also to meet practical needs of getting people in uniform and keeping them there longer as the military branches faced years of struggles filling the ranks.
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    Many major reforms were described by the officials who implemented them as driven by that need; when former Defense Secretary Ash Carter opened up combat roles to women in 2015, he said the military “cannot afford to cut ourselves off from half the country’s talents and skills” if it wanted to succeed in national defense.
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    And while the military had made changes in recent years in an attempt to lessen instances of harassment, discrimination or toxic leadership by creating reporting mechanisms so that troops would come forward, Hegseth said those efforts went too far and were undercutting commanders.

    “The definition of ‘toxic’ has been turned upside down, and we’re correcting that,” Hegseth vowed on Tuesday, adding that the Defense Department would be undertaking a review of words like “hazing” and “bullying” which he said had been “weaponized.”
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  2. The scale of these recent attacks means Ukraine needs any help it can get to minimize the impacts – and volunteers are playing an increasingly important role in the defensive mix.
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    Civilians are forming units tasked with shooting down smaller drones with machine guns or, most recently, specially developed interceptor drones.
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    The chief of staff of one of Kyiv’s volunteer formation legions, Andriy, whose call-sign is Stolyar, said his unit is composed of people from all walks of life – from construction workers to businessmen to poets.

    He told CNN the training for his legion lasts for about six weeks and includes basic knowledge, simulator practice and topography lessons. Andriy asked for his last name not to be published for security reasons.

    “A person must understand how to operate an aircraft. Drones are becoming increasingly complex – this is aviation, and it requires constant attention, knowledge, and skills,” he said.
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  3. Target is in trouble. And while it’s easy to get lost in the company’s recent (poor) handling of American culture war narratives that cast it as too “woke” or too willing to cave to online fascists, the root of Target’s problems runs deep.
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    Don’t get me wrong – the massive consumer boycotts from Black organizers have done damage. And there are probably folks on the far right who think even Target’s toned-down, overwhelmingly beige Pride merch this year was still too loud.
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    But its stock is in the gutter and sales have been falling for two years because of good ol’ business fundamentals. It overstocked. It lost the pulse of its customers. It went up against Amazon Prime with… actually, does anyone know what Target’s Amazon Prime competitor is called?
    The brand we petite bourgeoisie once playfully referred to as Tar-zhay has lost its spark. The company reported a decline in sales for a third-straight quarter, part of a broader trend of falling or flat sales for two years. Employees have lost confidence in the company’s direction. And 2025 has been a particularly rough financially, as Black shoppers organized a boycott over Target’s decision to cave to right-wing pressure on diverse hiring goals.
    Shares were down 10% Wednesday.

    It’s not to say the new guy, Michael Fiddelke, is unqualified. He’s been at Target since he started as an intern more than 20 years ago, after all. But Wall Street is clearly concerned that Target’s leadership is underestimating the severity of the need for a significant change— just as President Donald Trump’s tariffs on imported goods threaten the entire retail industry.

    Appointing a company lifer “does not necessarily remedy the problems of entrenched groupthink and the inward-looking mindset that have plagued Target for years,” Neil Saunders, an analyst at GlobalData Retail, said in a note to clients Wednesday.

    Missing the mark
    In its 2010s heyday, Target became a go-to for consumers who liked a bargain but didn’t necessarily like bargain-hunting. The shelves felt well-curated. You’d go to Target because it had one thing you needed and 12 things you didn’t know you needed. It was stocked with Millennial cringe long before Gen Z gave us the term Millennial cringe.

    Target’s sales held strong through the pandemic as remote workers set up home offices and stocked up on essentials. Months of lockdown also benefited the store as people began refreshing their spaces because they didn’t really have much else to do and they were staring at the same walls all the time.

  4. Astronomers first discovered Cha 1107-7626 in 2008, and since then, they have observed it with different telescopes to learn more about how the infant planet evolves, as well as to study its surroundings.
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    The research team observed the planet with Webb in 2024, making a clear detection of the surrounding disk. Next, the researchers studied it using the X-shooter spectrograph on the Very Large Telescope, which can capture different wavelengths of light emitted by an object ranging from ultraviolet to near-infrared.

    The observations detected a puzzling event as the planet transitioned from a steady accretion rate in April and May to a burst of growth between June and August.
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    “I fully expected that this is a short-term event, because those are much more common,” Scholz said. “When the burst kept going through July and August, I was absolutely stunned.”

    Follow-up observations made using the Webb telescope also showed that the chemistry of the disk had changed. Water vapor, present during the growth spurt, wasn’t in the disk before. Webb is the only telescope capable of capturing such detailed changes in the environment for such a faint object, Scholz said. Prior to this research, astronomers had only ever seen the chemistry of a disk change around a star, but not around a planet.

    Comparing observations from before and during the event showed that magnetic activity seems to be the main driver behind how much gas and dust is falling on the planet — a phenomenon typically associated with stars as they grow.

    But the new observations suggest that objects with much less mass than stars — the rogue world is less than 1% the mass of our sun — can have strong magnetic fields capable of driving the growth of the object, according to the study authors.

    An infrared image taken with the Visible and Infrared Telescope for Astronomy shows Cha 1107-7626, a dot located in the center.
    An infrared image taken with the Visible and Infrared Telescope for Astronomy shows Cha 1107-7626, a dot located in the center. ESO/Meingast et al.
    A planet that acts like a star
    The origin of rogue planets remains murky. It’s possible they are planets that are kicked out of orbit around stars due to the gravitational influence of other objects. Or perhaps they are the lowest-mass objects that happen to form like stars. For Cha 1107-7626, astronomers said they think it’s the latter.

    “This object most likely formed in a way similar to stars — from the collapse and fragmentation of a molecular cloud,” Scholz said.

    A molecular cloud is a massive, cold cloud of gas and dust that can stretch for hundreds of light-years, according to NASA.

    “We’re struck by quite how much the infancy of free-floating planetary-mass objects resembles that of stars like the Sun,” Jayawardhana said in a statement. “Our new findings underscore that similarity, and imply that some objects comparable to giant planets form the way stars do, from contracting clouds of gas and dust accompanied by disks of their own, and they go through growth episodes just like newborn stars.”

  5. Astronomers have observed a planet that in some ways behaves more like a star — including a massive growth spurt unlike anything witnessed before in a free-floating planet.
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    The rogue planet, which does not orbit any star, is called Cha 1107-7626 and is outside of our solar system, 620 light-years from Earth in the Chamaeleon constellation. A single light-year, or the distance light travels in one year, is equal to 5.88 trillion miles (9.46 trillion kilometers).

    The planet has a mass five to 10 times that of Jupiter, the largest planet in our solar system. And it’s getting bigger every second, according to new research published Thursday in The Astrophysical Journal Letters.

    Estimated to be 1 million to 2 million years old, Cha 1107-7626 is still forming, said study coauthor Aleks Scholz, an astronomer at the University of St. Andrews in Scotland. It may sound old, but astronomically speaking, the planet is in its infancy. By contrast, the planets in our solar system are about 4.5 billion years old.
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    Cha 1107-7626 is surrounded by a disk of gas and dust, which constantly falls onto the planet and accumulates during a process that astronomers call accretion. But the rate at which the young planet is growing varies, the study authors said.

    Observations with the European Southern Observatory’s Very Large Telescope in Chile’s Atacama Desert, along with follow-up views conducted by the James Webb Space Telescope, showed that the planet is adding material about eight times faster than a few months earlier and gobbling up gas and dust at a record rate of 6.6 billion tons (6 billion metric tons) per second.

    Related article
    The Earth-size exoplanet TRAPPIST-1 e, depicted at the lower right, is silhouetted as it passes in front of its flaring host star in this artist’s concept of the TRAPPIST-1 system.
    Earth-like exoplanet could be habitable, and astronomers may know soon

    The unusual burst of activity is the strongest growth rate ever recorded for a planet of any kind, said lead study author Victor Almendros-Abad, an astronomer at the Palermo Astronomical Observatory of the National Institute for Astrophysics in Italy, and is shedding light on the tumultuous formation and evolution of planets.

    “We’ve caught this newborn rogue planet in the act of gobbling up stuff at a furious pace,” said senior coauthor Ray Jayawardhana, provost and professor of physics and astronomy at Johns Hopkins University, in a statement.

    “Monitoring its behavior over the past few months, with two of the most powerful telescopes on the ground and in space, we have captured a rare glimpse into the baby phase of isolated objects not much heftier than Jupiter. Their infancy appears to be much more tumultuous than we had realized.”

  6. Astronomers first discovered Cha 1107-7626 in 2008, and since then, they have observed it with different telescopes to learn more about how the infant planet evolves, as well as to study its surroundings.
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    The research team observed the planet with Webb in 2024, making a clear detection of the surrounding disk. Next, the researchers studied it using the X-shooter spectrograph on the Very Large Telescope, which can capture different wavelengths of light emitted by an object ranging from ultraviolet to near-infrared.

    The observations detected a puzzling event as the planet transitioned from a steady accretion rate in April and May to a burst of growth between June and August.
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    “I fully expected that this is a short-term event, because those are much more common,” Scholz said. “When the burst kept going through July and August, I was absolutely stunned.”

    Follow-up observations made using the Webb telescope also showed that the chemistry of the disk had changed. Water vapor, present during the growth spurt, wasn’t in the disk before. Webb is the only telescope capable of capturing such detailed changes in the environment for such a faint object, Scholz said. Prior to this research, astronomers had only ever seen the chemistry of a disk change around a star, but not around a planet.

    Comparing observations from before and during the event showed that magnetic activity seems to be the main driver behind how much gas and dust is falling on the planet — a phenomenon typically associated with stars as they grow.

    But the new observations suggest that objects with much less mass than stars — the rogue world is less than 1% the mass of our sun — can have strong magnetic fields capable of driving the growth of the object, according to the study authors.

    An infrared image taken with the Visible and Infrared Telescope for Astronomy shows Cha 1107-7626, a dot located in the center.
    An infrared image taken with the Visible and Infrared Telescope for Astronomy shows Cha 1107-7626, a dot located in the center. ESO/Meingast et al.
    A planet that acts like a star
    The origin of rogue planets remains murky. It’s possible they are planets that are kicked out of orbit around stars due to the gravitational influence of other objects. Or perhaps they are the lowest-mass objects that happen to form like stars. For Cha 1107-7626, astronomers said they think it’s the latter.

    “This object most likely formed in a way similar to stars — from the collapse and fragmentation of a molecular cloud,” Scholz said.

    A molecular cloud is a massive, cold cloud of gas and dust that can stretch for hundreds of light-years, according to NASA.

    “We’re struck by quite how much the infancy of free-floating planetary-mass objects resembles that of stars like the Sun,” Jayawardhana said in a statement. “Our new findings underscore that similarity, and imply that some objects comparable to giant planets form the way stars do, from contracting clouds of gas and dust accompanied by disks of their own, and they go through growth episodes just like newborn stars.”

  7. Дизайнерский ремонт: искусство преображения пространства

    Дизайн интерьера играет важную роль в создании комфортной и уютной атмосферы в доме. Сегодня мы поговорим о таком понятии, как дизайнерский ремонт, который позволяет превратить обычное жилье в уникальное пространство, отражающее индивидуальность владельца.
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    Что такое дизайнерский ремонт?

    Дизайнерский ремонт — это комплекс работ, направленных на создание оригинального дизайна помещения. Это не просто обновление отделки, а полноценный творческий процесс, включающий разработку концепции, подбор материалов и мебели, а также реализацию проекта.

    Ключевые особенности дизайнерского ремонта:
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    – Индивидуальный подход к каждому проекту.
    – Использование качественных материалов и современных технологий.
    – Создание уникального стиля, соответствующего вкусам заказчика.
    – Оптимизация пространства для максимального комфорта и функциональности.

    Виды дизайнерских ремонтов

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    Существует несколько видов дизайнерских ремонтов, каждый из которых имеет свои особенности и преимущества.

    #1 Дизайнерский ремонт квартиры

    Это наиболее распространенный вид ремонта, подходящий для тех, кто хочет обновить интерьер своей городской квартиры. Специалисты разрабатывают проект, учитывая размеры помещений, пожелания клиента и бюджет. Такой ремонт включает перепланировку, замену коммуникаций, отделочные работы и декорирование.

    Пример дизайна: светлая гостиная с панорамными окнами, минималистичный дизайн кухни и спальни в стиле лофт.

    #2 Дизайнерский ремонт дома

    Такой ремонт предполагает полное преобразование жилого дома, начиная от фундамента и заканчивая крышей. Здесь важно учитывать архитектурные особенности здания, климатические условия региона и предпочтения владельцев. Часто используется экодизайн, натуральные материалы и энергосберегающие технологии.

    Пример дизайна: просторный холл с камином, стеклянная веранда с видом на сад, спальня в пастельных тонах.

    #3 Дизайнерский ремонт виллы

    Ремонт вилл требует особого подхода, поскольку такие объекты часто расположены в живописных местах и имеют большую площадь. Важно сохранить гармонию с окружающей средой, используя природные материалы и цвета. Особое внимание уделяется созданию зон отдыха, бассейнов и садов.

    Пример дизайна: роскошная вилла с бассейном, открытая терраса с видами на море, спальная зона в тропическом стиле.

    #4 Дизайнерский ремонт коттеджа

    Коттедж отличается от обычного дома наличием придомового участка и возможностью организации дополнительных функциональных зон. Ремонт коттеджей включает работу над фасадом, ландшафтом и внутренним пространством. Стили могут варьироваться от классики до хай-тека.

    Пример дизайна: двухэтажный коттедж с мансардой, гостиная-столовая в скандинавском стиле, детская комната с игровой зоной.

    #5 Дизайнерский ремонт пентхауса

    Пентхаус — это элитное жилье, расположенное на верхних этажах зданий с панорамными видами. Для такого типа недвижимости характерны высокие потолки, большие окна и эксклюзивные элементы декора. Проектирование пентхауса требует учета особенностей конструкции здания и пожеланий клиентов относительно приватности и удобства.

    Пример дизайна: современный пентхаус с открытой планировкой, кабинет с видом на город, зона отдыха с джакузи.

    Заключение

    Дизайнерский ремонт — это возможность создать идеальное пространство для жизни и отдыха. Независимо от того, хотите ли вы обновить квартиру, дом, виллу, коттедж или пентхаус, профессиональный подход гарантирует вам комфорт и эстетическое удовольствие на долгие годы.
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  8. Lying down and vomiting between courses: This is how Ancient Romans would feast
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    Imagine, if you will, the most glorious festive feast, with an oversize turkey, stuffing two ways, holiday ham, the requisite fixings and at least half a dozen pies and cakes. That may all sound grand — that is, until you consider the extravagant displays of the ancient Roman banquet.

    Members of the Roman upper classes regularly indulged in lavish, hours-long feasts that served to broadcast their wealth and status in ways that eclipse our notions of a resplendent meal. “Eating was the supreme act of civilization and celebration of life,” said Alberto Jori, professor of ancient philosophy at the University of Ferrara in Italy.
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    Ancient Romans enjoyed sweet and salty concoctions. Lagane, a rustic short pasta usually served with chickpeas, was also used to make a honey cake with fresh ricotta cheese. The Romans used garum, a pungent, salty fermented fish sauce for umami flavor in all dishes, even as a dessert topping. (For context, garum has a similar flavor profile and composition to current-day Asian fish sauces such as Vietnam’s nuoc mam and Thailand’s nam pla.) The prized condiment was made by leaving fish meat, blood and guts to ferment inside containers under the Mediterranean sun.
    Game meat such as venison, wild boar, rabbit and pheasant along with seafood like raw oysters, shellfish and lobster were just some of the pricey foods that made regular appearances at the Roman banquet.

    What’s more, hosts played a game of one-upmanship by serving over-the-top, exotic dishes like parrot tongue stew and stuffed dormouse. “Dormouse was a delicacy that farmers fattened up for months inside pots and then sold at markets,” Jori said. “While huge quantities of parrots were killed to have enough tongues to make fricassee.”
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    Giorgio Franchetti, a food historian and scholar of ancient Roman history, recovered lost recipes from these repasts, which he shares in “Dining With the Ancient Romans,” written with “archaeo-cook” Cristina Conte. Together, the duo organize dining experiences at archaeological sites in Italy that give guests a taste of what eating like a Roman noble was all about. These cultural tours also delve into the eyebrow-raising rituals that accompanied these meals.

  9. Дизайнерский ремонт: искусство преображения пространства

    Дизайн интерьера играет важную роль в создании комфортной и уютной атмосферы в доме. Сегодня мы поговорим о таком понятии, как дизайнерский ремонт, который позволяет превратить обычное жилье в уникальное пространство, отражающее индивидуальность владельца.
    дизайнерский ремонт однокомнатной квартиры
    Что такое дизайнерский ремонт?

    Дизайнерский ремонт — это комплекс работ, направленных на создание оригинального дизайна помещения. Это не просто обновление отделки, а полноценный творческий процесс, включающий разработку концепции, подбор материалов и мебели, а также реализацию проекта.

    Ключевые особенности дизайнерского ремонта:
    дизайнерский ремонт дома под ключ москва
    – Индивидуальный подход к каждому проекту.
    – Использование качественных материалов и современных технологий.
    – Создание уникального стиля, соответствующего вкусам заказчика.
    – Оптимизация пространства для максимального комфорта и функциональности.

    Виды дизайнерских ремонтов

    дизайнерский ремонт дома под ключ москва

    Существует несколько видов дизайнерских ремонтов, каждый из которых имеет свои особенности и преимущества.

    #1 Дизайнерский ремонт квартиры

    Это наиболее распространенный вид ремонта, подходящий для тех, кто хочет обновить интерьер своей городской квартиры. Специалисты разрабатывают проект, учитывая размеры помещений, пожелания клиента и бюджет. Такой ремонт включает перепланировку, замену коммуникаций, отделочные работы и декорирование.

    Пример дизайна: светлая гостиная с панорамными окнами, минималистичный дизайн кухни и спальни в стиле лофт.

    #2 Дизайнерский ремонт дома

    Такой ремонт предполагает полное преобразование жилого дома, начиная от фундамента и заканчивая крышей. Здесь важно учитывать архитектурные особенности здания, климатические условия региона и предпочтения владельцев. Часто используется экодизайн, натуральные материалы и энергосберегающие технологии.

    Пример дизайна: просторный холл с камином, стеклянная веранда с видом на сад, спальня в пастельных тонах.

    #3 Дизайнерский ремонт виллы

    Ремонт вилл требует особого подхода, поскольку такие объекты часто расположены в живописных местах и имеют большую площадь. Важно сохранить гармонию с окружающей средой, используя природные материалы и цвета. Особое внимание уделяется созданию зон отдыха, бассейнов и садов.

    Пример дизайна: роскошная вилла с бассейном, открытая терраса с видами на море, спальная зона в тропическом стиле.

    #4 Дизайнерский ремонт коттеджа

    Коттедж отличается от обычного дома наличием придомового участка и возможностью организации дополнительных функциональных зон. Ремонт коттеджей включает работу над фасадом, ландшафтом и внутренним пространством. Стили могут варьироваться от классики до хай-тека.

    Пример дизайна: двухэтажный коттедж с мансардой, гостиная-столовая в скандинавском стиле, детская комната с игровой зоной.

    #5 Дизайнерский ремонт пентхауса

    Пентхаус — это элитное жилье, расположенное на верхних этажах зданий с панорамными видами. Для такого типа недвижимости характерны высокие потолки, большие окна и эксклюзивные элементы декора. Проектирование пентхауса требует учета особенностей конструкции здания и пожеланий клиентов относительно приватности и удобства.

    Пример дизайна: современный пентхаус с открытой планировкой, кабинет с видом на город, зона отдыха с джакузи.

    Заключение

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    Это наиболее распространенный вид ремонта, подходящий для тех, кто хочет обновить интерьер своей городской квартиры. Специалисты разрабатывают проект, учитывая размеры помещений, пожелания клиента и бюджет. Такой ремонт включает перепланировку, замену коммуникаций, отделочные работы и декорирование.

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    #3 Дизайнерский ремонт виллы

    Ремонт вилл требует особого подхода, поскольку такие объекты часто расположены в живописных местах и имеют большую площадь. Важно сохранить гармонию с окружающей средой, используя природные материалы и цвета. Особое внимание уделяется созданию зон отдыха, бассейнов и садов.

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    #4 Дизайнерский ремонт коттеджа

    Коттедж отличается от обычного дома наличием придомового участка и возможностью организации дополнительных функциональных зон. Ремонт коттеджей включает работу над фасадом, ландшафтом и внутренним пространством. Стили могут варьироваться от классики до хай-тека.

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  18. What we’re covering
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    In New York City, democratic socialist Zohran Mamdani’s win marked the second time this year he’d defeated former Gov. Andrew Cuomo — first in the Democratic primary, and then in the general election, with Cuomo running as an independent backed by Trump.
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    The Democratic wins by candidates with sharp ideological differences will do little to settle the party’s long-raging internal debate about its way forward, with a host of competitive midterm primaries just months away and the 2028 presidential primary already looming.

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    In California, voters approved by a wide margin a redistricting ballot measure intended to boost Democrats’ chances in next year’s battle for control of the House. And in Pennsylvania, Democratic state Supreme Court justices won their retention votes, allowing Democrats to keep their majority on the high court in a perennial battleground state where legal challenges over voting rules are all but certain.
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